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Journal Articles

Thermodynamic study on redox reactions of boiling nitric acid solutions

Kato, Chiaki; Kiuchi, Kiyoshi; Sugimoto, Katsuhisa*

Corrosion Engineering, 52(1), p.69 - 85, 2003/01

It is necessary to know the generation mechanism of high equilibrium potential in the solutions. Existing nitrogen oxides in nitric acid solutions were first analyzed by Raman spectroscopy and then existing amount of nitrogen oxides were examined by thermodynamic calculation using the SOLGASMIX software. The Raman spectroscopic analysis showed that the existing amount of un-dissociated HNO$$_{3}$$ increased with increasing nitric acid concentration and solution temperature. The thermodynamic calculation showed that the important nitrogen oxides in nitric acid solutions are HNO$$_{3}$$, NO$$_{3}$$$$^{-}$$, HNO$$_{2}$$, NO$$_{2}$$, and NO. The equilibrium potential of nitric acid solutions is, however, mainly decided by the HNO$$_{3}$$/HNO$$_{2}$$ equilibrium. The thermodynamic calculation also suggested that the increased oxidization potential on the heat-transfer surface is attributed to the reduction of nitrous acid concentration by the thermal decomposition of nitrous acid on the surface and the continuous removal of decomposition product from the solutions by boiling bubbles.

Journal Articles

Thermodynamic study on redox reactions of boiling nitric acid solutions

Kato, Chiaki; Kiuchi, Kiyoshi; Sugimoto, Katsuhisa*

Zairyo To Kankyo, 52(1), p.44 - 52, 2003/01

In order to understand corrosion of metals in nitric acid solutions, it is necessary to know the generation mechanism of high equilibrium potential in the solutions, especially under boiling conditions. The Raman spectroscopic analysis showed that the existing amount of un-dissociated HNO$$_{3}$$ increased with increasing nitric acid concentration and solution temperature. The existing amount of NO$$_{2}$$ also increased by thermal decomposition. The thermodynamic calculation showed that the important nitrogen oxides in nitric acid solutions are HNO$$_{3}$$, NO$$_{3}^{-}$$, HNO$$_{2}$$, NO$$_{2}$$, and NO. The equilibrium potential of nitric acid solutions is, however, mainly decided by the HNO$$_{3}$$/HNO$$_{2}$$ equilibrium. The thermodynamic calculation also suggested that the increased oxidization potential on the heat-transfer surface is attributed to the reduction of nitrous acid concentration by the thermal decomposition of nitrous acid on the surface and the continuous removal of decomposition product from the solutions by boiling bubbles.

Journal Articles

Flue gas treatment

Sunaga, Hiromi

Denki Gakkai Gijutsu Hokoku, (895), p.61 - 62, 2002/09

no abstracts in English

Journal Articles

Journal Articles

Flue gas treatment

Namba, Hideki

Hoshasen Riyo Ni Okeru Saikin No Shimpo, p.162 - 172, 2000/06

no abstracts in English

Journal Articles

Electron beam treatment of contaminated gases

Hashimoto, Shoji

Denki Gakkai-Shi, 119(5), p.278 - 280, 1999/05

no abstracts in English

Journal Articles

Electron beam irradiation technology for purification of flue gas

Tokunaga, Okihiro

Kankyo To Shoenerugi No Tameno Enerugi Shingijutsu Taikei, 0, p.506 - 508, 1996/00

no abstracts in English

Journal Articles

Electron beam purification of flue gas; Pilot-scale tests

Tokunaga, Okihiro

Genshiryoku Kogyo, 41(7), p.24 - 29, 1995/00

no abstracts in English

Journal Articles

Electron beam treatment of ventilation exhaust from tunnel

Tokunaga, Okihiro

Hoshasen To Sangyo, 0(66), p.59 - 60, 1995/00

no abstracts in English

Journal Articles

Pilot-scale test on electron beam treatment of municipal solid waste flue gas with spraying slaked-lime slurry

*; Hirota, Koichi; *; *; *; *; *; *; *; Miyata, Teijiro; et al.

Radiation Physics and Chemistry, 45(6), p.1021 - 1027, 1995/00

 Times Cited Count:7 Percentile:59.15(Chemistry, Physical)

no abstracts in English

Journal Articles

Electron beam irradiation technology for purification of flue gas

Tokunaga, Okihiro

Seidenki Gakkai-Shi, 19(4), p.296 - 300, 1995/00

no abstracts in English

Journal Articles

Electron beam treatment of flue gas from a municipal waste incinerator

Tokunaga, Okihiro; *; *

Hoshasen To Sangyo, 0(58), p.15 - 19, 1993/00

no abstracts in English

Journal Articles

The Study on electron beam flue gas treatment for coal-fired thermal plant in Japan

Namba, Hideki; Tokunaga, Okihiro; *; *; *; *

Radiation Physics and Chemistry, 42(4-6), p.669 - 672, 1993/00

 Times Cited Count:15 Percentile:79.48(Chemistry, Physical)

no abstracts in English

Journal Articles

Pilot-plant for NO$$_{x}$$, SO$$_{2}$$, and HCl removal from flue-gas ofmunicipal waste incinerator by electron beam irradiation

*; *; *; Tokunaga, Okihiro; Miyata, Teijiro; Hirota, Koichi; *; *; *; *

Radiation Physics and Chemistry, 42(4-6), p.679 - 682, 1993/00

 Times Cited Count:6 Percentile:55.97(Chemistry, Physical)

no abstracts in English

Journal Articles

Electron beam treatment of flue gas

Tokunaga, Okihiro

Isotope News, 0(450), p.8 - 11, 1991/12

no abstracts in English

Journal Articles

Basic study on electron beam flue gas treatment for coal-fired thermal plant

Namba, Hideki; Tokunaga, Okihiro; *; *; *; *

Proceedings of the International Conference on Evolution in Beam Applications, 0, p.476 - 481, 1991/11

no abstracts in English

Journal Articles

Basic study on electron beam treatment of coal-fired flue gas

Namba, Hideki; Tokunaga, Okihiro; H.-R.Paur*

Journal of Aerosol Science, 22(1), p.475 - 478, 1991/00

no abstracts in English

Journal Articles

Feature of flue gas treatment by electron-beam irradiation and details of its development

;

Kogai To Taisaku, 22(6), p.537 - 543, 1986/00

no abstracts in English

Journal Articles

Effects of some powdery materials on NO$$_{x}$$ removal in electron beam treatment of exhaust gases

; ;

Kogai To Taisaku, 19(2), p.158 - 164, 1983/00

no abstracts in English

31 (Records 1-20 displayed on this page)